Nonuniqueness of canonical ensemble theory arising from microcanonical basis

نویسندگان

  • Sumiyoshi Abe
  • A. K. Rajagopal
چکیده

Given physical systems, counting rule for their statistical mechanical descriptions need not be unique, in general. It is shown that this nonuniqueness leads to the existence of various canonical ensemble theories, which equally arise from the definite microcanonical basis. Thus, the Gibbs theorem for canonical ensemble theory is not universal, and maximum entropy principle is to be appropriately modified for each physical context.

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تاریخ انتشار 1999